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91.
This paper analyzes the properties of reflected polarization dependent loss of apodized fiber Bragg gratings with temperature effective. We simulates reflected spectrum and polarization dependent loss of the apodized fiber Bragg gratings. The reflected spectrum and polarization dependent loss are measured under different temperatures. The analysis results show that reflected polarization dependent loss presents two peaks which shift an equal proportion to long wavelength with temperature increasing and have very good stability so we propose an idea that use polarization dependent loss as temperature sensor measurement parameters. The results show that the accuracy of measurement can be increased almost by one order of magnitude. 相似文献
92.
93.
An efficient, ligand- and metal-oxidant-free, one-pot, cascade aerobic oxidative, palladium-catalyzed, multicomponent reaction has been developed through isocyanide insertion of less active secondary amide and aromatic amine, which leads to 2-amino-substituted-4(3H)-quinazolinones. This approach proves to be one of the simplest methods for the synthesis of this class of valuable bioactive heterocyclic scaffolds. 相似文献
94.
V. Venkataramasubramanian 《合成通讯》2013,43(18):2099-2105
A concise and efficient synthesis of (±)-clopidogrel, an antithrombotic agent, is achieved by inserting CO2 at the benzylic position as the key reaction without using any toxic transition metals. The overall yield of the synthetic process is 38% and the salient features include operationally simple process chemistry and fewer steps. 相似文献
95.
96.
A semi-empirical method is proposed to calculate the ion ranges in energy region E?=?0.025–10?MeV/nucleon. The dependence of ion ranges on the projectile nuclear charge, mass and velocity is analysed. The calculations presented for ranges of ions with nuclear charges Z?=?2–10 in silicon are compared with SRIM results and experimental data. 相似文献
97.
Thomas C. Schelling 《The Journal of mathematical sociology》2013,37(2):143-186
Some segregation results from the practices of organizations, some from specialized communication systems, some from correlation with a variable that is non‐random; and some results from the interplay of individual choices. This is an abstract study of the interactive dynamics of discriminatory individual choices. One model is a simulation in which individual members of two recognizable groups distribute themselves in neighborhoods defined by reference to their own locations. A second model is analytic and deals with compartmented space. A final section applies the analytics to ‘neighborhood tipping.’ The systemic effects are found to be overwhelming: there is no simple correspondence of individual incentive to collective results. Exaggerated separation and patterning result from the dynamics of movement. Inferences about individual motives can usually not be drawn from aggregate patterns. Some unexpected phenomena, like density and vacancy, are generated. A general theory of ‘tipping’ begins to emerge. 相似文献
98.
《数学研究通讯:英文版》2016,(4):325-331
In this paper, we consider the problem of determining the order of INAR(q) model on the basis of the Bayesian estimation theory. The Bayesian es-timator for the order is given with respect to a squared-error loss function. The consistency of the estimator is discussed. The results of a simulation study for the estimation method are presented. 相似文献
99.
Dr. Ze-Jie Lv Wei Liu Miaomiao Zhu Zhengqi Chai Junnian Wei Prof. Wen-Xiong Zhang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(66):16498-16504
Although the reaction chemistry of transition metallacyclopropenes has been well-established in the last decades, the reactivity of rare-earth metallacyclopropenes remains elusive. Herein, we report the reaction of lutetacyclopropene 1 toward a series of unsaturated molecules. The reaction of 1 with one equiv. of PhCOMe, Ar1CHO (Ar1=2,6-Me2C6H3), W(CO)6, and PhCH=NPh provided oxalutetacyclopentenes, metallacyclic lutetoxycarbene, and azalutetacyclopentene via 1,2-insertion of C=O, C≡O, or C=N bonds into Lu−Csp2 bond, respectively. However, the reaction between 1 and Ar2N=C=NAr2 (Ar2=4-MeC6H4) gave an acyclic lutetium complex with a diamidinate ligand by the coupling of one molecule of 1 with two carbodiimides, irrespective of the amount of carbodiimide employed. More interestingly, when 1 was treated with two equiv. of Ar1CHO, the reductive coupling of two C=O bonds was discovered to give a lutetium pinacolate complex along with the release of tolan. Remarkably, the reactivity of 1 is significantly different from that of scandacyclopropenes; these metallacycles derived from 1 all represent the first cases in rare-earth organometallic chemistry. 相似文献
100.